Manufacturing Fit-for-Purpose Membranes from Nanostructured Polymers

By William Phillip

Chemical and Biomolecular Engineering, University of Notre Dame, Notre Dame, IN

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Abstract

The use of non-traditional sources of water (e.g., seawater and wastewater) is essential to supporting human life on earth. While seawater desalination will remain an indispensable technology, its large energy demand necessitates the development of complementary wastewater treatment strategies. Fit-for-purpose water, one envisioned opportunity, utilizes distributed treatment systems to provide water for localized reuse at the potable or non-potable quality demanded by its intended application. Membranes fabricated from self-assembled block polymers provide a versatile platform that can help address the technical hurdles associated with this emerging paradigm. In this presentation, we will discuss how to produce block polymers membranes that contain a high density of well-defined nanoscale pores using facile and scalable techniques. Furthermore, we will describe how the performance profile of the membranes can be tailored to effect selective separations through affinity-based adsorption, electrostatic interactions, and catalytic conversion of target solutes.

Bio

William A. Phillip William A. Phillip received his B.S. in Chemical Engineering from the University of Notre Dame in 2004. Based on a strong suggestion from his undergraduate research advisor, Dr. Arvind Varma, Dr. Phillip went to the University of Minnesota for graduate school. There, under the guidance of Dr. Ed Cussler, he completed his Ph.D. in Chemical Engineering in 2009. Following his Ph.D., Dr. Phillip completed a postdoctoral appointment with Dr. Menachem Elimelech at Yale University. He is currently an Associate Professor in the Department of Chemical and Biomolecular Engineering at the University of Notre Dame, where he heads the Water purification and Advanced Transport Engineering Research (WATER) laboratory. Dr. Phillip is a member of the Editorial Advisory Board for ACS Applied Polymer Materials.

The WATER lab examines how the structure and chemistry of polymeric membranes affect the transport of solutes and solvents across them. By understanding the connection between functionality and property, Professor Phillip and his group are able to design and fabricate next-generation membranes that provide more precise control over the transport of chemical species. These material advantages are then leveraged to design systems capable of enhancing chemical separations at the water-energy nexus. The WATER lab has been recognized with the 3M Non-Tenured Faculty Award, the Army Research Office Young Investigator Program, the North American Membrane Society Young Membrane Scientist Award, the DuPont Young Professor Award, the Rev. Edmund P. Joyce, C.S.C., Award for Excellence in Undergraduate Teaching, and the FRI/John G. Kunesh Award.

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Researchers should cite this work as follows:

  • William Phillip (2019), "Manufacturing Fit-for-Purpose Membranes from Nanostructured Polymers," https://nanohub.org/resources/31788.

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Location

Forney Hall, Room G140, Purdue University, West Lafayette, IN

Tags

Manufacturing Fit-for-Purpose Membranes from Nanostructured Polymers
  • Manufacturing Functional Membranes from Nanostructured Polymers 1. Manufacturing Functional Membr… 0
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  • Acknowledgements 2. Acknowledgements 430.5638972305639
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  • Acknowledgements 3. Acknowledgements 573.57357357357364
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  • Why WATER? Because Water is a Global Issue 4. Why WATER? Because Water is a … 579.87987987987992
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  • The 5. The "Big" Conclusions 753.45345345345345
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  • Seawater RO Desalination Produces Drinking Water 6. Seawater RO Desalination Produ… 830.93093093093091
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  • Seawater RO Desalination Produces Drinking Water 7. Seawater RO Desalination Produ… 872.93960627293961
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  • Seawater RO Desalination Produces Drinking Water 8. Seawater RO Desalination Produ… 958.89222555889228
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  • Applied Pressure Determines Power Consumption 9. Applied Pressure Determines Po… 1003.4701368034702
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  • Seawater RO Power Consumption is Reaching Limit 10. Seawater RO Power Consumption … 1070.6039372706039
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  • Seawater RO Power Consumption is Reaching Limit 11. Seawater RO Power Consumption … 1127.2272272272273
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  • Current Standard for Membrane Separations 12. Current Standard for Membrane … 1205.2385719052386
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  • Membrane Separations Are Versatile 13. Membrane Separations Are Versa… 1280.1468134801469
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  • Size-Selective Filtration Membranes 14. Size-Selective Filtration Memb… 1358.4250917584252
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  • A Versatile Platform: Self-Assembled Block Polymers 15. A Versatile Platform: Self-Ass… 1406.373039706373
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  • Synthetic Control Used to Target Morphology 16. Synthetic Control Used to Targ… 1478.2115448782115
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  • Current Standard for Membrane Separation Processes 17. Current Standard for Membrane … 1515.0817484150819
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  • Modules Seek to Increase Membrane Area per Volume 18. Modules Seek to Increase Membr… 1561.3613613613613
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  • Membranes are Cast Using a NIPS Process 19. Membranes are Cast Using a NIP… 1627.7277277277278
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  • Membranes are Cast Using a SNIPS Process 20. Membranes are Cast Using a SNI… 1702.4357691024359
    00:00/00:00
  • Membranes are Cast Using a SNIPS Process 21. Membranes are Cast Using a SNI… 1808.3083083083084
    00:00/00:00
  • Modules Seek to Increase Membrane Area per Volume 22. Modules Seek to Increase Membr… 1844.0774107440775
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  • Combining the SNIPS Process with Dip-Coating 23. Combining the SNIPS Process wi… 1877.1771771771773
    00:00/00:00
  • Process Control Can be Used to Tune Permeability, LP 24. Process Control Can be Used to… 1960.7941274607942
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  • Synthetic Control Can be Used to Tune Pore Size 25. Synthetic Control Can be Used … 2080.3470136803471
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  • Synthetic Control Can be Used to Tune Pore Size 26. Synthetic Control Can be Used … 2122.3223223223222
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  • Synthetic Control Can be Used to Tune Pore Size 27. Synthetic Control Can be Used … 2160.0266933600269
    00:00/00:00
  • Proper Molecular Design Enhances Chlorine Resistance 28. Proper Molecular Design Enhanc… 2332.9662996329662
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  • New Opportunities for Membrane Separations 29. New Opportunities for Membrane… 2426.6599933266602
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  • New Opportunities for Membrane Separations 30. New Opportunities for Membrane… 2516.7834501167836
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  • Functional Membrane Separations Are Versatile 31. Functional Membrane Separation… 2549.7831164497834
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  • Control of End Block Enables Functionalization 32. Control of End Block Enables F… 2614.4477811144479
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  • Control of End Block Enables Functionalization 33. Control of End Block Enables F… 2633.2999666333
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  • 1. Charge-Functionalized Membranes Reject Dissolved Ions 34. 1. Charge-Functionalized Membr… 2654.0540540540542
    00:00/00:00
  • 1. Molecular Simulations Capture Essential Phenomena 35. 1. Molecular Simulations Captu… 2695.4954954954956
    00:00/00:00
  • 2. Membrane Sorbents Capture and Release Solutes Quickly 36. 2. Membrane Sorbents Capture a… 2812.9462796129465
    00:00/00:00
  • 2. Resilient Removal of Heavy Metal Ion Contamination 37. 2. Resilient Removal of Heavy … 2893.5935935935936
    00:00/00:00
  • 4. Controlling the Deposition of Alkyne-Terminated Reactants 38. 4. Controlling the Deposition … 2976.2095428762095
    00:00/00:00
  • 4. Toward Multifunctional Membranes 39. 4. Toward Multifunctional Memb… 3120.9209209209212
    00:00/00:00
  • 4. Antifouling, Valence-selective Dual-functional Membranes 40. 4. Antifouling, Valence-select… 3219.3193193193192
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  • 4. Dual-functional Membranes Exhibit Reduced Fouling, High Rejection 41. 4. Dual-functional Membranes E… 3274.0073406740075
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  • 5. Inkjet Printing of Charge-Patterned Mosaic Membranes 42. 5. Inkjet Printing of Charge-P… 3344.9449449449453
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  • 5. Inkjet Printing of Charge-Patterned Mosaic Membranes 43. 5. Inkjet Printing of Charge-P… 3346.1127794461131
    00:00/00:00
  • 5. Inkjet Printing of Charge-Patterned Mosaic Membranes 44. 5. Inkjet Printing of Charge-P… 3346.5131798465131
    00:00/00:00
  • 5. Local Variations in Potential Direct Ions Toward Membrane Surface 45. 5. Local Variations in Potenti… 3347.0804137470805
    00:00/00:00
  • 5. Interfacial Junctions Control Electrolyte Transport 46. 5. Interfacial Junctions Contr… 3347.6476476476478
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  • The 47. The "Big" Conclusions 3348.6152819486156
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  • Molecular-to-Systems Engineering 48. Molecular-to-Systems Engineeri… 3377.5775775775778
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  • Questions? 49. Questions? 3378.1781781781783
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  • Molecular-to-Systems Engineering 50. Molecular-to-Systems Engineeri… 3663.4968301634972
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