Critical Measurements to Enable the Use of Polymers in Membranes, Composites, and Impact Mitigation

By Christopher L. Soles

Functional Polymers Group, National Institute of Standards and Technology (NIST), Gaithersburg, MD

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Abstract

New polymeric materials are being developed for a wide-range of applications where their functional properties play a critical role in advancing performance of the technology. Examples that are of interested to my research group include polymer matrix composites with improved mechanical properties at the fiber-matrix interface under hot-wet conditions, transport membranes that can selectively transport or separate specific species for applications at the energy-water nexus, and tough polymers that mitigate impact. In support of the NIST mission, develop advanced measurement methods that facilitate development and commercial deployment of polymeric materials in these areas of technological and societal importance. We work closely with industry to identify the technical roadblocks inhibiting these technologies and then work with materials developers to identify and validate design cues that are needed design new and improved polymers that advance the state-of-the-art. In this presentation I will present an overview of my research groups activities in these three areas, highlighting the importance of polymer structure and dynamics in establishing the functional properties of the polymers that enable the technology. For the sake of this presentation, I will emphasize the importance of polymeric materials for advanced transport membranes for technologies at the energy-water nexus, including fuel cells, desalination and water purification, and chemical separations. We will discuss in details the different transport mechanics of water, ions, and small molecule solvents in these different systems, describing the similarities and differences. We will make the case that understanding the mechanisms of transport at the molecular scale is critical for optimizing the transport mechanisms in these different situations and developing the design cues that are needed to design new membranes.

Bio

Christopher L. Soles Dr. Christopher L. Soles leads the Functional Polymers Group in the Materials Measurement Laboratory at the National Institute of Standards and Technology (NIST). His research group focuses on measurement strategies that help commercialize the use polymeric materials in technologies related to semiconductor fabrication, printed and flexible electronics, membranes for ion transport and water filtration, structural composites, and impact mitigation. His research in all these areas has always focused on the relationship between polymer dynamics and material function in these technology sectors. He received Bachelor of Science degrees in both Mechanical Engineering (ME) and Materials Science and Engineering (MSE) in 1993, and his Doctorate in MSE in 1998, all from the University of Michigan. He then moved to the NIST Polymers Division as a NRC Postdoctoral Fellow, making the transition to a Staff Scientist in 2002. For the past 10 years he has led the Functional Polymers Group in the Materials Science and Engineering Division.

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Cite this work

Researchers should cite this work as follows:

  • Christopher L. Soles (2019), "Critical Measurements to Enable the Use of Polymers in Membranes, Composites, and Impact Mitigation," https://nanohub.org/resources/30088.

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Time

Location

Burton Morgan, Room 121, Purdue University, West Lafayette, IN

Tags

Critical Measurements to Enable the Use of Polymers in Membranes, Composites, and Impact Mitigation
  • Critical Measurements to Enable the Use of Polymers in Membranes, Composites, & Impact Mitigation 1. Critical Measurements to Enabl… 0
    00:00/00:00
  • Functional Polymers Group 2. Functional Polymers Group 85.051718385051728
    00:00/00:00
  • Polymer Matrix Composites Project - Overview 3. Polymer Matrix Composites Proj… 170.60393727060395
    00:00/00:00
  • The Influence of Polymer Dynamics on the Functional Properties of Materials for Impact Mitigation 4. The Influence of Polymer Dynam… 298.19819819819821
    00:00/00:00
  • Polymer Mechanics Project - Overview 5. Polymer Mechanics Project - Ov… 308.84217550884216
    00:00/00:00
  • Contributors - Polymer Mechanics 6. Contributors - Polymer Mechani… 381.44811478144811
    00:00/00:00
  • Polymers for Impact Mitigation 7. Polymers for Impact Mitigation 414.38104771438105
    00:00/00:00
  • High Strain Rate Impact Testing 8. High Strain Rate Impact Testin… 530.36369703036371
    00:00/00:00
  • Quasielastic Neutron Scattering at NIST 9. Quasielastic Neutron Scatterin… 675.67567567567573
    00:00/00:00
  • Incoherent Neutron Scattering 10. Incoherent Neutron Scattering 796.7967967967968
    00:00/00:00
  • Plasticized Polycarbonates 11. Plasticized Polycarbonates 829.2625959292626
    00:00/00:00
  • Polycarbonate with Arochlor 12. Polycarbonate with Arochlor 992.45912579245919
    00:00/00:00
  • Modified Polycarbonates 13. Modified Polycarbonates 1106.2395729062396
    00:00/00:00
  • Modified Polycarbonates 14. Modified Polycarbonates 1154.8548548548549
    00:00/00:00
  • Fast Dynamics & Impact in Polycarbonates 15. Fast Dynamics & Impact in Poly… 1199.0657323990658
    00:00/00:00
  • Key Observations 16. Key Observations 1325.9259259259259
    00:00/00:00
  • Modified Polycarbonates 17. Modified Polycarbonates 1336.0026693360028
    00:00/00:00
  • Modified Polycarbonates 18. Modified Polycarbonates 1358.4918251584918
    00:00/00:00
  • Modified Polycarbonates 19. Modified Polycarbonates 1365.2318985652319
    00:00/00:00
  • Modified Polycarbonates 20. Modified Polycarbonates 1415.6489823156489
    00:00/00:00
  • Modified Polycarbonates 21. Modified Polycarbonates 1491.157824491158
    00:00/00:00
  • Modified Polycarbonates 22. Modified Polycarbonates 1542.6092759426094
    00:00/00:00
  • Modified Polycarbonates 23. Modified Polycarbonates 1560.7273940607274
    00:00/00:00
  • Modified Polycarbonates 24. Modified Polycarbonates 1576.4764764764766
    00:00/00:00
  • Modified Polycarbonates 25. Modified Polycarbonates 1587.4874874874874
    00:00/00:00
  • Modified Polycarbonates – Ductile to Brittle Transition (DBT) 26. Modified Polycarbonates – Du… 1616.6833500166833
    00:00/00:00
  • Modified Polycarbonates 27. Modified Polycarbonates 1753.1531531531532
    00:00/00:00
  • Does this make sense? 28. Does this make sense? 1755.1885218551886
    00:00/00:00
  • Conclusions 29. Conclusions 1824.3576910243578
    00:00/00:00
  • Characterization and Measurement Needs in Polymeric Transport Membranes 30. Characterization and Measureme… 1826.0260260260261
    00:00/00:00
  • Contributors – Transport Membranes 31. Contributors – Transport Mem… 1835.7357357357357
    00:00/00:00
  • Goals for this Section 32. Goals for this Section 1884.784784784785
    00:00/00:00
  • Polymer Membranes with Controlled Transport Properties 33. Polymer Membranes with Control… 1942.0086753420087
    00:00/00:00
  • Membrane Transport Mechanisms 34. Membrane Transport Mechanisms 2099.3660326993663
    00:00/00:00
  • Membrane Transport Mechanisms 35. Membrane Transport Mechanisms 2116.5832499165836
    00:00/00:00
  • Membrane Transport Mechanisms 36. Membrane Transport Mechanisms 2128.4617951284617
    00:00/00:00
  • Membrane Transport Mechanisms 37. Membrane Transport Mechanisms 2146.2128795462131
    00:00/00:00
  • Issues when trying to understand transport 38. Issues when trying to understa… 2161.4948281614948
    00:00/00:00
  • Relative Humidity Scale 39. Relative Humidity Scale 2243.8104771438107
    00:00/00:00
  • It's Complicated 40. It's Complicated 2302.102102102102
    00:00/00:00
  • Structure & Chemistry 41. Structure & Chemistry 2351.8852185518854
    00:00/00:00
  • Materials Systems 42. Materials Systems 2382.8828828828828
    00:00/00:00
  • Epoxy Network Variations 43. Epoxy Network Variations 2455.1885218551888
    00:00/00:00
  • Positron Annihilation Lifetime Spectroscopy 44. Positron Annihilation Lifetime… 2496.696696696697
    00:00/00:00
  • PALS and Equilibrium Moisture Uptake 45. PALS and Equilibrium Moisture … 2554.120787454121
    00:00/00:00
  • PALS and Moisture Diffusivity 46. PALS and Moisture Diffusivity 2667.4674674674675
    00:00/00:00
  • PALS & Gas Permeability in Amorphous Thermoplastics 47. PALS & Gas Permeability in Amo… 2736.9703036369706
    00:00/00:00
  • Quasielastic Neutron Scattering at NIST 48. Quasielastic Neutron Scatterin… 2783.5502168835505
    00:00/00:00
  • Dry Epoxy Mean Square Atomic Displacements 49. Dry Epoxy Mean Square Atomic D… 2792.9262595929263
    00:00/00:00
  • Water Diffusivity & Dry Epoxy Mean Square Displacement 50. Water Diffusivity & Dry Epoxy … 2817.7510844177514
    00:00/00:00
  • Water Diffusivity & Dry Epoxy Mean Square Displacement 51. Water Diffusivity & Dry Epoxy … 2907.3406740073406
    00:00/00:00
  • Membranes for Water Filtration 52. Membranes for Water Filtration 2909.9766433099767
    00:00/00:00
  • Commercial PA Membranes Fabrication 53. Commercial PA Membranes Fabric… 2921.3213213213216
    00:00/00:00
  • Model PA Membranes for Quantitative Measurements 54. Model PA Membranes for Quantit… 2985.9526192859526
    00:00/00:00
  • X-Ray Reflectivity 55. X-Ray Reflectivity 3050.8842175508844
    00:00/00:00
  • X-Ray Reflectivity for Swelling 56. X-Ray Reflectivity for Swellin… 3056.38972305639
    00:00/00:00
  • X-Ray Reflectivity for Swelling 57. X-Ray Reflectivity for Swellin… 3068.5685685685685
    00:00/00:00
  • Blob Model of Network Swelling 58. Blob Model of Network Swelling 3072.1721721721724
    00:00/00:00
  • Blob Model for Network Swelling 59. Blob Model for Network Swellin… 3072.8061394728061
    00:00/00:00
  • Blob Model for Network Swelling 60. Blob Model for Network Swellin… 3142.1755088421755
    00:00/00:00
  • Effects of Film Thickness on PA Swelling 61. Effects of Film Thickness on P… 3145.7791124457794
    00:00/00:00
  • PALS for Nanoscale Porosity (network pore) 62. PALS for Nanoscale Porosity (n… 3185.2852852852852
    00:00/00:00
  • SANS for Nanoscale Porosity (aggregate pore) 63. SANS for Nanoscale Porosity (a… 3211.644978311645
    00:00/00:00
  • SANS for Nanoscale Porosity (aggregate pore) 64. SANS for Nanoscale Porosity (a… 3234.3009676343013
    00:00/00:00
  • SANS for Nanoscale Porosity (aggregate pore) 65. SANS for Nanoscale Porosity (a… 3240.8742075408745
    00:00/00:00
  • (PVBTMA)(Br)-b-(PMB) Diblock Copolymer AEMs 66. (PVBTMA)(Br)-b-(PMB) Diblock C… 3300.2335669002337
    00:00/00:00
  • Water Distributions in the PVTBMA Domains 67. Water Distributions in the PVT… 3330.5972639305974
    00:00/00:00
  • Inelastic Neutron Scattering 68. Inelastic Neutron Scattering 3371.6383049716383
    00:00/00:00
  • Isolating Water Dynamics from Polymer with QENS 69. Isolating Water Dynamics from … 3397.097097097097
    00:00/00:00
  • Water Dynamics in a Diverse Set Hydrated Membranes 70. Water Dynamics in a Diverse Se… 3442.676009342676
    00:00/00:00
  • Water Dynamics in a Diverse Set Hydrated Membranes 71. Water Dynamics in a Diverse Se… 3504.4377711044381
    00:00/00:00
  • Water Dynamics in a Diverse Set Hydrated Membranes 72. Water Dynamics in a Diverse Se… 3543.8772105438775
    00:00/00:00
  • Key Takeaways from this talk 73. Key Takeaways from this talk 3651.0844177510844
    00:00/00:00
  • Structure & Chemistry 74. Structure & Chemistry 3723.6236236236236
    00:00/00:00