Development of Iontronics

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Abstract

Electric field control of charge carrier density has long been a key technology to  tune the physical properties of condensed matter, exploring the modern semiconductor industry. One of the big challenges is to increase the maximum attainable carrier density, however it is limited by the quality of gate dielectrics. In this talk, I'm going to show the novel technique to modulate carrier density making use of ionic liquid electrolytes. With electrolyte gating, we can modulate up to 10^15/cm2 of carrier density at the interface which is 2 orders of magnitude larger than conventional gate dielectrics and demonstrate that we can indeed control metal-to-insulator and ferromagnetic-paramagnetic transition by electric-field effect doping. I also will show our recent progress (energy harvester and light emitting device) using ionic liquid electrolytes.

Bio

Dr. Shimpei Ono is working at Central Research Institute of Electric Power Industry as senior research scientist and has been involved for the last 10 years in the research of novel electronics with ionic liquids. He is also a visiting professor at the University of Grenoble Alps within the framework of Chair of Excellence program with LANEF.

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Researchers should cite this work as follows:

  • (2018), "Development of Iontronics," https://nanohub.org/resources/27719.

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Time

Location

Room 2001, Birck Nanotechnology Center, Purdue University, West Lafayette, IN

Development of Iontronics
  • Development of iontronics 1. Development of iontronics 0
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  • Where is CRIEPI? 2. Where is CRIEPI? 88.655321988655331
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  • Yokosuka Area 3. Yokosuka Area 131.664998331665
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  • What is iontronics? 4. What is iontronics? 174.94160827494162
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  • Introduction 5. Introduction 230.26359693026362
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  • Chemical doping 6. Chemical doping 306.33967300633969
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  • Limitation of Chemical doping 7. Limitation of Chemical doping 374.24090757424091
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  • Electric-field effect 8. Electric-field effect 445.11177844511178
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  • Electric field effect 9. Electric field effect 503.40340340340344
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  • Why we need electrolyte gating? 10. Why we need electrolyte gating… 539.70637303970636
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  • Fake experiments were done!!! 11. Fake experiments were done!!! 647.64764764764766
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  • To overcome the limitations Let's use electrolyte 12. To overcome the limitations Le… 685.18518518518522
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  • Why we use electrolytes? 13. Why we use electrolytes? 694.76142809476141
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  • History of electrolyte gating 14. History of electrolyte gating 763.66366366366367
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  • New tools to study solid state physics!! 15. New tools to study solid state… 787.52085418752085
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  • New tools to study solid state physics!! 16. New tools to study solid state… 880.28028028028029
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  • Electric-field induced superconductivity 17. Electric-field induced superco… 983.04971638304971
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  • Cut & stick methods 18. Cut & stick methods 1006.272939606273
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  • What we can do? 19. What we can do? 1055.5889222555891
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  • How to choose the optimal ionic liquids Case for OFETs 20. How to choose the optimal ioni… 1091.4581247914582
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  • Introduction 21. Introduction 1129.7297297297298
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  • What is necessary for real application? 22. What is necessary for real app… 1191.2245578912246
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  • Ionic liquids gating 23. Ionic liquids gating 1267.7677677677677
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  • What is the optimal ionic liquids for OFETs? 24. What is the optimal ionic liqu… 1359.8598598598599
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  • Various capacitance of ionic liquids 25. Various capacitance of ionic l… 1461.8284951618286
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  • Electrochemical window 26. Electrochemical window 1516.7167167167168
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  • What is the optimal ionic liquids for OFETs? Effect of anion for p-type semiconductor 27. What is the optimal ionic liqu… 1553.2866199532866
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  • High-density carrier doping with ionic liquids 28. High-density carrier doping wi… 1567.1338004671338
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  • Structure of OFETs 29. Structure of OFETs 1613.6136136136138
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  • Which ionic liquids is best so far? 30. Which ionic liquids is best so… 1689.0223556890223
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  • What is the optimal ionic liquids for OFETs? Effect of cation for p-type semiconductor 31. What is the optimal ionic liqu… 1783.1831831831833
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  • Let's fix the anion and change cation!! 32. Let's fix the anion and change… 1800.4671338004673
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  • Effect of ILs for p-type semiconductor 33. Effect of ILs for p-type semic… 1821.1211211211212
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  • Discussion 34. Discussion 1862.6960293626962
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  • Why it happened? 35. Why it happened? 1874.6413079746415
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  • X-ray reflectivity experments 36. X-ray reflectivity experments 1965.1985318651987
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  • What is the optimal ionic liquids for OFETs? What is the case for n-type semiconductors? 37. What is the optimal ionic liqu… 2012.3456790123457
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  • Effect of ILs for n-type semiconductor 38. Effect of ILs for n-type semic… 2029.2959626292961
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  • Discussion 39. Discussion 2034.2342342342342
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  • Discussion 40. Discussion 2043.4100767434102
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  • Why slope is different? 41. Why slope is different? 2076.7434100767437
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  • To further increase mobility (n-type) 42. To further increase mobility (… 2146.47981314648
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  • Discussion 43. Discussion 2176.0760760760763
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  • Best performance of OFETs with ionic liquids 44. Best performance of OFETs with… 2199.2992992992995
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  • Where are we now ? 45. Where are we now ? 2229.1291291291291
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  • Complementary inverter 46. Complementary inverter 2230.4304304304305
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  • Summary 47. Summary 2255.1551551551552
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  • Light-emitting electrochemical cell with ionic liquids 48. Light-emitting electrochemical… 2299.2659325992659
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  • Mechanism of LEC 49. Mechanism of LEC 2322.5558892225558
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  • Light-emitting electrochemical cell 50. Light-emitting electrochemical… 2417.4174174174177
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  • Why ionic liquids? 51. Why ionic liquids? 2466.4330997664333
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  • Low voltage operation 52. Low voltage operation 2575.9426092759427
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  • What is the next generation of iontronics? Electric double layer electret 53. What is the next generation of… 2623.9239239239241
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  • What is Electric double layer Electret? 54. What is Electric double layer … 2656.8902235568903
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  • Energy harvester with Electric double layer electret 55. Energy harvester with Electric… 2763.5635635635635
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  • Demonstration 56. Demonstration 2813.0797464130796
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  • Best performance so far 57. Best performance so far 2840.8742075408745
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  • Summary 58. Summary 2997.897897897898
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  • Summary 59. Summary 3001.7684351017688
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  • Let's start new collaborations 60. Let's start new collaborations 3056.9903236569903
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  • Low voltage operation 61. Low voltage operation 3091.8251584918253
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  • What is Electric double layer Electret? 62. What is Electric double layer … 3244.3109776443112
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  • Energy harvester with Electric double layer electret 63. Energy harvester with Electric… 3250.9509509509512
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  • Mechanism of LEC 64. Mechanism of LEC 3377.5775775775778
    00:00/00:00
  • What is Electric double layer Electret? 65. What is Electric double layer … 3448.7821154487824
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